A shear thinning, or pseudoplastic, medium is one that exhibits decreased viscosity when shear stress is applied. The most common example is probably ketchup. Turn the bottle upside down, and the contents stay put. Give the bottle a knock, and annoyingly half the bottle pours out. The same phenomenon is in action when a great landslide results from just a small shaking (i.e. quake) when the area resides on clay ground. Paints also rely on this phenomenon: they are runny when brushed or rolled, but become viscous as soon as the pressure is removed, and thus don't run down the wall.
Following Peter Barham's idea, I had another look in Beckett's "Science of chocolate", which confirmed that chocolate is shear thinning (I suspect that Barham indeed refers to Beckett). In addition, when the softened chocolate firms up again, after just a few seconds, it recrystallises in the same crystal form as before. This is important, because heating-cooling sequences (such as when melting melting) might lead to blooming, such as fat bloom.
My idea was hence: is it possible to use this property to shape chocolate and still avoid the need for apparently laborious and complicated tempering?
My only available equipment for applying shear stress on such a hard medium as chocolate was our kitchen machine with the meat grinder/mincer attached. Running the chocolate through this grinder, the result was what I've termed "chocolate twigs":
Comments on the result
I'm fairly content with the result, but my detailed knowledge of crafting chocolate isn't good enough for me to do a proper evaluation. Even though the texture seems fine, still a nice snap when braking, the colour and surface structure is changed. Maybe that's just OK? However, there are some relevant points to consider:
- The point is applying shear pressure, and not melting the chocolate
- 55% dark chocolate worked fine, whereas milk chocolate softens too much in the grinder (becomes pasty)
- the metal grinder needs to be kept cool, since grinding generates heat and might melt the chocolate. Cooling can be done by wrapping a cold moist cloth around the grinder
- the chocolate was kept at room temperature overnight (20-25 °C), but taking the chocolate directly from the fridge did also work (in a previous experiment)
You need quite a lot of chocolate to produce a moderate amount of twigs. In the video above, I spent 400 g. However, the chocolate may be run several times through the grinder. The rest is of course perfectly OK for making other chocolate-based stuff, or maybe practice tempering chocolate...
Coarse or fine mincing screens?
The coarse screen (8 mm holes) was the only one that worked in my hands, as the finer ones resulted in too much resistance. Too much resistance results in clogging and eventually warming/melting the chocolate.
Our Kenwood Major (800 W) did the job, but I felt that I overloaded it slightly, especially when it clogged. Dark chocolate is really hard stuff. It'd been fun having some professional extrusion equipment with enough power and temperature regulation allowing to make various shapes. Barham mentions using a pasta machine for "shear shaping" chocolate, but I doubt it'll be strong enough to shape the chocolate, rather than crumble it. Maybe it'll work with milk chocolate?
I didn't find any directly relevant scientific literature on this, and the two only references I've found mentioning this (briefly) are
Barham: "The science of cooking"
Beckett: "The science of chocolate"
Also, Corriher's "Cookwise" has quite a lot of information on dealing with chocolate (again, I've still not got my hands on a copy of Bakewise, unfortunately)
That's very cool! So the chocolate flakes you put into the grinder actually join together seamlessly?ReplyDelete
In a way, yes. The initial structure is broken down, and the chocolate takes on a new one. As seen from the closeups, one might say that the chocolate is kneaded together. However, the structure becomes somewhat porous and the surface gloss is lost. Maybe that'll be different if one uses proper extrusion equipment (I should guess so). Simply, a new product arises and it's up to anyone to exploit the possibilities...ReplyDelete
Thank you for sharing this information.ReplyDelete
It will really helpful to solve my confusion
Process $ Chemical Engineering